Appendix E: Schedule 2 - List of Dangerous Goods

Column 1

Shipping Name and Description — This column gives the shipping names for dangerous goods in alphabetical order within each primary class and within each packing group. The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. The most appropriate designation for the dangerous goods must be selected based on each class, UN number and packing group established per the classification requirements of clause 4.5.

Column 2

Primary Class — This column gives the primary class of the dangerous goods.

Column 3

UN Number — This column gives the UN number assigned to the dangerous goods under the UN system.

Column 4

Packing Group — This column gives the packing groups of the dangerous goods.

Column 5

Special Provisions — This column gives the special provisions that apply to the dangerous goods.

Symbol P

The symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited.

Class 2.1 Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Dimethylamine, anhydrous	2.1	UN1032	—	5, 6, 8, 63
Ethylamine	2.1	UN1036	—	4, 63
Ethylene, refrigerated liquid	2.1	UN1038	—	69
Hydrogen, refrigerated liquid	2.1	UN1966	—	69
Methane, compressed or Natural gas, compressed, with high methane content	2.1	UN1971	—	5, 8, 9
Methane, refrigerated liquid or natural gas, refrigerated liquid, with high methane content	2.1	UN1972	—	69
Methylacetylene and propadiene mixture, stabilized	2.1	UN1060	—	4, 29, 63
Methylamine, anhydrous	2.1	UN1061	—	5, 6, 8, 63
Methyl chloride (R40)	2.1	UN1063	—	5, 6, 8, 63
Petroleum gases, liquefied	2.1	UN1075	—	4, 61, 63, 77
Vinyl chloride, stabilized	2.1	UN1086	—	4, 29, 63
Vinyl fluoride, stabilized	2.1	UN1860	—	5, 58, 59, 63
Vinyl methyl ether, stabilized	2.1	UN1087	—	4, 29, 63
Dangerous Goods of Class 2.1, not listed above, non-cryogenic	2.1	—	—	4, 63

Class 2.2 Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Air, refrigerated liquid	2.2	UN1003	—	70
Ammonia solutions, relative density less than 0.880 at 15°C (59°F) in water, with more than 35% but not more than 50% ammonia	2.2	UN2073	—	5, 8, 9
Argon, refrigerated liquid	2.2	UN1951	—	70
Carbon dioxide, refrigerated liquid	2.2	UN2187	—	5, 55, 56
Gases, refrigerated liquid, n.o.s.	2.2	UN3158	—	70
Helium, refrigerated liquid	2.2	UN1963	—	70
Krypton, refrigerated liquid	2.2	UN1970	—	70
Neon, refrigerated liquid	2.2	UN1913	—	70
Nitrogen, compressed	2.2	UN1066	—	5, 8, 9
Nitrogen, refrigerated liquid	2.2	UN1977	—	70
Nitrous oxide, refrigerated liquid	2.2	UN2201	—	5, 14, 55, 56
Oxygen, refrigerated liquid	2.2	UN1073	—	70
Sulphur hexafluoride	2.2	UN1080	—	4, 84
Xenon, refrigerated liquid	2.2	UN2591	—	70
Dangerous Goods of Class 2.2, not listed above, non-cryogenic	2.2	—	—	4

Class 2.3 Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Ammonia, anhydrous	2.3	UN1005	—	5, 6, 8, 9, 60, 61, 75, 79, 80, 81, 83
Ammonia solutions, relative density less than 0.880 at 15°C (59°F) in water, with more than 50% ammonia	2.3	UN3318	—	5, 6, 8, 9, 60, 75, 79, 80, 81, 83
Boron trichloride	2.3	UN1741	—	5, 6, 17, 19, 74
Boron trifluoride, compressed	2.3	UN1008	—	4, 17, 19, 73
Chlorine	2.3	UN1017	—	5, 6, 19, 51, 64, 73, 83
Chloropicrin and methyl bromide mixture	2.3	UN1581	—	4, 17, 19, 73
Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone B	2.3	—	—	4, 19, 73, 82, 83
Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone C	2.3	—	—	4, 17, 19, 74, 80, 83
Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone D	2.3	—	—	4, 17, 19, 75, 80, 81, 83
Dinitrogen tetroxide, or Nitrogen dioxide	2.3	UN1067	—	5, 7, 15, 19, 30, 40, 72, 80, 83
Ethylene oxide or Ethylene oxide, with nitrogen	2.3	UN1040	—	11, 75, 80, 83
Hydrogen chloride, refrigerated liquid	2.3	UN2186	—	5, 14, 57, 62, 74, 83
Hydrogen sulphide	2.3	UN1053	—	5, 7, 17, 19, 63, 65, 73, 83
Methyl bromide	2.3	UN1062	—	5, 6, 19, 74, 80, 83
Methylchlorosilane	2.3	UN2534	—	4, 17, 19, 63, 73
Methyl mercaptan	2.3	UN1064	—	5, 6, 15, 19, 63, 74, 80, 83
Nitrosyl chloride	2.3	UN1069	—	5, 6, 19, 52, 53, 74, 80, 83
Phosgene	2.3	UN1076	—	6, 15, 38, 72
Sulphur dioxide, liquefied or Sulphur dioxide	2.3	UN1079	—	5, 7, 19, 51, 74, 80, 83
Sulphuryl fluoride	2.3	UN2191	—	5, 54, 75
Trifluoroacetyl chloride	2.3	UN3057	—	4, 17, 19, 73
Trifluorochloroethylene, stabilized	2.3	UN1082	—	4, 19, 63, 74
Dangerous Goods of Class 2.3, not listed above	2.3	—	—	P

Class 3 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Acetaldehyde	3	UN1089	I	3, 21
Acrylonitrile, stabilized	3	UN1093	I	3, 17
Allyl chloride	3	UN1100	I	3, 66
tert-Butyl isocyanate	3	UN2484	I	5, 7, 17, 19
Carbon disulphide	3	UN1131	I	3, 21
Chloroprene, stabilized	3	UN1991	I	3, 36
Dimethylhydrazine, symmetrical or 1,2-Dimethylhydrazine	3	UN2382	I	4, 17, 19
Ethyl isocyanate	3	UN2481	I	5, 7, 17, 19, 44, 72
Flammable liquid, n.o.s.	3	UN1993	I	3
Isopropyl isocyanate	3	UN2483	I	5, 7, 17, 19, 44, 72
Methacrylonitrile, stabilized	3	UN3079	I	4, 17, 19, 44, 73
Methoxymethyl isocyanate	3	UN2605	I	5, 7, 17, 19, 44, 72
Methyltrichlorosilane	3	UN1250	I	3, 14
Organochlorine pesticide, liquid, flammable, toxic, flash point less than 23°C (73°F)	3	UN2762	I	3, 66
Petroleum crude oil	3	UN 1267	I	3
Petroleum sour crude oil, flammable, toxic	3	UN 3494	I	3
n-Propyl isocyanate	3	UN2482	I	5, 7, 17, 19
Vinyltrichlorosilane, stabilized	3	UN1305	I	3, 14
Dangerous Goods of Class 3, Packing Group I, not listed above	3	—	I	3

Class 3 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Alcohols, n.o.s.	3	UN 1987	II	3
1,1-Dichloroethane	3	UN2362	II	3, 66
1,2-Dichloroethylene	3	UN1150	II	3, 66
Ethanol and gasoline mixture, with more than 10 percent ethanol	3	UN 3475	II	3
Ethylene dichloride	3	UN1184	II	3, 66
Flammable liquid, n.o.s.	3	UN1993	II	3
Isobutyl isocyanate	3	UN2486	II	5, 7, 17, 19, 44, 72
4-Methylmorpholine or n-Methylmorpholine	3	UN2535	II	3, 14
Organochlorine pesticide, liquid, flammable, toxic, flashpoint less than 23°C (73°F)	3	UN2762	II	3, 66
Petroleum crude oil	3	UN 1267	II	3
Petroleum sour crude oil, flammable, toxic	3	UN 3494	II	3
Dangerous Goods of Class 3, Packing Group II, not listed above	3	—	II	3

Class 3 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Alcohols, n.o.s.	3	UN 1987	III	3, 12
Chlorobenzene	3	UN1134	III	3, 66
Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5°C (141°F), at or above its flashpoint	3	UN3256	III	67
Flammable liquid, n.o.s.	3	UN1993	III	3, 12
Petroleum crude oil	3	UN 1267	III	3, 12
Petroleum sour crude oil, flammable, toxic	3	UN 3494	III	3
Dangerous Goods of Class 3, Packing Group III, not listed above	3	—	III	3, 12
Dangerous Goods of Class 4.1, Packing Group I	4.1	—	I	P

Class 4.1 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Aluminum powder, coated	4.1	UN1309	II	1
Cerium, slabs, ingots or rods	4.1	UN1333	II	1
Ferrocerium	4.1	UN1323	II	1
Flammable solid, corrosive, organic, n.o.s.	4.1	UN2925	II	1
Flammable solid, organic, n.o.s.	4.1	UN1325	II	1
Flammable solid, toxic, organic, n.o.s.	4.1	UN2926	II	3
Lead phosphite, dibasic	4.1	UN2989	II	1
Metal hydrides, flammable, n.o.s.	4.1	UN3182	II	1
Metal powder, flammable, n.o.s.	4.1	UN3089	II	1
Phosphorus sesquisulphide, free from yellow and white phosphorus	4.1	UN1341	II	1
Rubber scrap or Rubber shoddy, powdered or granulated, not greater than 840 mm and rubber content greater than 45%	4.1	UN1345	II	1
Solids containing flammable liquid, n.o.s.	4.1	UN3175	II	1
Titanium hydride	4.1	UN1871	II	2
Dangerous Goods of Class 4.1, Packing Group II, not listed above	4.1	—	II	P

Class 4.1 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Aluminum powder, coated	4.1	UN1309	III	1
Aluminum resinate	4.1	UN2715	III	1
Borneol	4.1	UN1312	III	1
Camphor, synthetic	4.1	UN2717	III	1
Cobalt naphthenates, powder	4.1	UN2001	III	1
Dicyclohexylammonium nitrite	4.1	UN2687	III	1
Flammable solid, corrosive, organic, n.o.s.	4.1	UN2925	III	3
Flammable solid, organic, n.o.s.	4.1	UN1325	III	1
Flammable solid, toxic, organic, n.o.s.	4.1	UN2926	III	3
Hexamethylenetetramine	4.1	UN1328	III	1
Lead phosphite, dibasic	4.1	UN2989	III	1
Magnesium or Magnesium alloys, with more than 50% magnesium, in pellets, turnings or ribbons	4.1	UN1869	III	1
Manganese resinate	4.1	UN1330	III	1
Metaldehyde	4.1	UN1332	III	1
Metal hydrides, flammable, n.o.s.	4.1	UN3182	III	1
Metal powder, flammable, n.o.s.	4.1	UN3089	III	1
Naphthalene, crude or Naphthalene, refined	4.1	UN1334	III	1
Naphthalene, molten	4.1	UN2304	III	2
Nitronaphthalene	4.1	UN2538	III	1
Paraformaldehyde	4.1	UN2213	III	1
Silicon powder, amorphous	4.1	UN1346	III	1
Sulphur	4.1	UN1350	III	1, 2
Sulphur, molten	4.1	UN2448	III	67
Titanium sponge granules or Titanium sponge powders	4.1	UN2878	III	1
Zinc resinate	4.1	UN2714	III	1
Dangerous Goods of Class 4.1, Packing Group III, not listed above	4.1	—	III	P

Class 4.2 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Organometallic substance, solid, pyrophoric, water-reactive	4.2	UN 3393	I	4,18
Organometallic substance, liquid, pyrophoric, water-reactive	4.2	UN 3394	I	4, 17, 18
Phosphorus white, molten	4.2	UN2447	I	3, 17, 25
Phosphorus, white or Phosphorus, yellow, dry or Phosphorous, yellow, in solution or Phosphorous, yellow, underwater	4.2	UN1381	I	3, 17, 25
Pyrophoric liquid, organic, n.o.s.	4.2	UN2845	I	4, 18
Titanium powder, dry	4.2	UN2546	I	3
Dangerous Goods of Class 4.2, Packing Group I, not listed above	4.2	—	I	P

Class 4.2 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Carbon, animal or vegetable origin	4.2	UN1361	II	3
Potassium sulphide, anhydrous or Potassium sulphide, with less than 30% water of crystallization	4.2	UN1382	II	2, 21
Self-heating solid, corrosive, organic, n.o.s.	4.2	UN3126	II	2
Self-heating solid, organic, n.o.s.	4.2	UN3088	II	2
Sodium dithionite or Sodium hydrosulphite	4.2	UN1384	II	2
Sodium methylate	4.2	UN1431	II	2
Sodium sulphide, anhydrous or Sodium sulphide, with less than 30% water of crystallization	4.2	UN1385	II	2
Titanium powder, dry	4.2	UN2546	II	2
Dangerous Goods of Class 4.2, Packing Group II, not listed above	4.2	—	II	P

Class 4.2 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Carbon, activated	4.2	UN1362	III	2
Carbon, animal or vegetable origin	4.2	UN1361	III	2
Copra	4.2	UN1363	III	2
Fibres or Fabrics, animal or vegetable or synthetic, n.o.s., with oil	4.2	UN1373	III	2
Hafnium powder, dry	4.2	UN2545	III	2
Iron oxide, spent or Iron sponge, spent, obtained from hydrocarbon gas purification	4.2	UN1376	III	1, 22
Seed cake, with more than 1.5% oil and not more than 11% moisture	4.2	UN1386	III	2
Seed cake, with not more than 1.5% oil and not more than 11% moisture	4.2	UN2217	III	2
Self-heating solid, corrosive, organic, n.o.s.	4.2	UN3126	III	3
Self-heating solid, organic, n.o.s.	4.2	UN3088	III	2
Self-heating solid, toxic, organic, n.o.s.	4.2	UN3128	III	3
Titanium powder, dry	4.2	UN2546	III	2
Zirconium scrap	4.2	UN1932	III	1
Dangerous Goods of Class 4.2, Packing Group III, not listed above	4.2	—	III	P

Class 4.3 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Aluminum phosphide	4.3	UN1397	I	3
Boron trifluoride dimethyl etherate	4.3	UN2965	I	3
Calcium carbide	4.3	UN1402	I	2, 34, 37
Ethyldichlorosilane	4.3	UN1183	I	4
Magnesium powder or Magnesium alloys, powder	4.3	UN1418	I	4, 35
Methyldichlorosilane	4.3	UN1242	I	3, 14
Methyl magnesium bromide in ethyl ether	4.3	UN1928	I	3
Potassium	4.3	UN2257	I	4, 26
Potassium, metal alloys	4.3	UN1420	I	4, 26
Potassium sodium alloys	4.3	UN1422	I	4, 26
Rubidium	4.3	UN1423	I	3, 13
Sodium	4.3	UN1428	I	5, 41
Trichlorosilane	4.3	UN1295	I	4
Dangerous Goods of Class 4.3, Packing Groups I, not listed above	4.3	—	I	P

Class 4.3 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Aluminum carbide	4.3	UN1394	II	3
Aluminum ferrosilicon powder	4.3	UN1395	II	3
Aluminum smelting by-products or Aluminum remelting by-products	4.3	UN3170	II	3, 78
Barium	4.3	UN1400	II	2
Calcium carbide	4.3	UN1402	II	2, 34, 37
Magnesium powder or Magnesium alloys, powder	4.3	UN1418	II	2, 35
Magnesium silicide	4.3	UN2624	II	2
Phosphorus pentasulphide, free from yellow and white phosphorus	4.3	UN1340	II	3, 37
Dangerous Goods of Class 4.3, Packing Groups II, not listed above	4.3	—	II	P

Class 4.3 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Aluminum smelting by-products or Aluminum remelting by-products	4.3	UN3170	III	3, 78
Aluminum silicon powder, uncoated	4.3	UN1398	III	2
Calcium cyanamide, with more than 0.1% Calcium carbide	4.3	UN1403	III	2
Calcium manganese silicon	4.3	UN2844	III	2
Ferrosilicon, with 30% or more but less than 90% silicon	4.3	UN1408	III	1
Magnesium granules, coated, particle size not less than 149 mm	4.3	UN2950	III	1
Magnesium powder or Magnesium alloys, powder	4.3	UN1418	III	2, 35
Dangerous Goods of Class 4.3, Packing Group III, not listed above	4.3	—	III	P

Class 5.1 Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Ammonium nitrate, liquid, hot concentrated solution	5.1	UN2426	—	3

Class 5.1 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Bromine pentafluoride	5.1	UN1745	I	5, 7, 17, 19, 44, 72
Bromine trifluoride	5.1	UN1746	I	4, 17, 19, 44, 73
Hydrogen peroxide, stabilized or Hydrogen peroxide, aqueous solutions, stabilized, with more than 60% hydrogen peroxide	5.1	UN2015	I	3, 32, 47
Iodine pentafluoride	5.1	UN2495	I	3
Oxidizing solid, corrosive, n.o.s.	5.1	UN3085	I	3
Oxidizing solid, n.o.s.	5.1	UN1479	I	3
Dangerous Goods of Class 5.1, Packing Group I, not listed above	5.1	—	I	P

Class 5.1 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water	5.1	UN2880	II	1
Chlorate and borate mixture	5.1	UN1458	II	1
Chlorate and magnesium chloride mixture	5.1	UN1459	II	1
Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts	5.1	UN2465	II	1
Hydrogen peroxide, aqueous solution, with more than 40% but not more than 60% hydrogen peroxide, stabilized, as necessary	5.1	UN2014	II	3, 32, 47
Hydrogen peroxide, aqueous solution, with not less than 20% but not more than 40% hydrogen peroxide, stabilized, as necessary	5.1	UN2014	II	3, 32
Potassium chlorate, aqueous solution	5.1	UN2427	II	2
Potassium nitrate and sodium nitrite mixture	5.1	UN1487	II	46
Sodium chlorate	5.1	UN1495	II	1
Sodium chlorate, aqueous solution	5.1	UN2428	II	2, 14
Dangerous Goods of Class 5.1, Packing Group II, not listed above	5.1	—	II	3
Dangerous Goods of Class 5.1, Packing Group II, Solids, not listed above, having no subsidiary class other than Class 9	5.1	—	II	1

Class 5.1 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Dangerous Goods of Class 5.1, Packing Group III, Liquids	5.1	—	III	2
Dangerous Goods of Class 5.1, Packing Group III, Solids	5.1	—	III	1

Class 5.2 Packing Group I Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Dangerous Goods of Class 5.2, Packing Group I	5.2	—	I	P

Class 5.2 Packing Group II Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Dangerous Goods of Class 5.2, Packing Group II	5.2	—	II	P

Class 5.2 Packing Group III Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Dangerous Goods of Class 5.2, Packing Group III	5.2	—	III	P

Class 6.1 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Acetone cyanohydrin, stabilized	6.1	UN1541	I	4, 7, 17, 19, 44, 45, 73
Acrolein, stabilized	6.1	UN1092	I	5, 7, 17, 19, 28, 44, 72
Allyl alcohol	6.1	UN1098	I	4, 17, 19, 44, 73
Allylamine	6.1	UN2334	I	4, 17, 19, 44, 73
Allyl chloroformate	6.1	UN1722	I	4, 17, 19, 44, 73
Arsenic trichloride	6.1	UN1560	I	4, 17, 19, 44, 73
n-Butyl isocyanate	6.1	UN2485	I	4, 17, 19, 44, 73
tert-Butyl isocyanate	6.1	UN2484	I	5, 7, 17, 19, 44, 72
Chloroacetone, stabilized	6.1	UN1695	I	4, 17, 19, 44, 73
Chloroacetyl chloride	6.1	UN1752	I	4, 16, 17, 19, 44, 73
2-Chloroethanal	6.1	UN2232	I	4, 17, 19, 44, 73
Chloropicrin	6.1	UN1580	I	4, 15, 17, 19, 44, 73
Crotonaldehyde, stabilized	6.1	UN1143	I	4, 17, 19, 44, 73
Cyclohexyl isocyanate	6.1	UN2488	I	4, 17, 19, 44, 73
Diketene, stabilized	6.1	UN2521	I	4, 17, 19, 44, 73
Dimethylhydrazine, symmetrical	6.1	UN2382	I	4, 17, 19, 44, 73
Dimethylhydrazine, unsymmetrical	6.1	UN1163	I	4, 15, 17, 19, 44, 73
Dimethyl sulphate	6.1	UN1595	I	4, 17, 19, 44, 73
Ethyl chloroformate	6.1	UN1182	I	4, 17, 19, 44, 73
Ethyldichloroarsine	6.1	UN1892	I	4, 17, 19, 44, 73
Ethylene chlorohydrin	6.1	UN1135	I	4, 17, 19, 44, 73
Ethylene dibromide	6.1	UN1605	I	4, 17, 19, 44, 73
Ethyleneimine, stabilized	6.1	UN1185	I	5, 7, 17, 19, 44, 72
Hexachlorocyclopentadiene	6.1	UN2646	I	4, 17, 19, 44, 73
Hydrocyanic acid, aqueous solution, with not more than 20% hydrogen cyanide	6.1	UN1613	I	4, 7, 39, 44, 73
Hydrogen cyanide, solution in alcohol, with not more than 45 percent hydrogen cyanide	6.1	UN3294	I	4, 17, 19, 44, 73
Hydrogen cyanide, stabilized, containing less than 3% water	6.1	UN1051	I	5, 7, 39, 44, 48, 72
Iron Pentacarbonyl	6.1	UN1994	I	5, 7, 17, 19, 44, 72
Isopropyl chloroformate	6.1	UN2407	I	4, 17, 19, 44, 73
Methanesulfonyl chloride	6.1	UN3246	I	4, 17, 19, 44, 73
Methyl bromide and ethylene dibromide mixture, liquid	6.1	UN1647	I	4, 17, 19, 44, 73
Methyl chloroformate	6.1	UN1238	I	5, 7, 17, 19, 44, 72
Methyl chloromethyl ether	6.1	UN1239	I	5, 7, 17, 19, 44, 72
2-Methyl-2-heptanethiol	6.1	UN3023	I	4, 17, 19, 44, 73
Methylhydrazine	6.1	UN1244	I	5, 7, 15, 17, 19, 44, 72
Methyl iodide	6.1	UN2644	I	4, 17, 19, 44, 73
Methyl isocyanate	6.1	UN2480	I	5, 7, 17, 19, 44, 72
Methyl isothiocyanate	6.1	UN2477	I	4, 17, 19, 44, 73
Methyl orthosilicate	6.1	UN2606	I	4, 17, 19, 44, 73
Methyl vinyl ketone, stabilized	6.1	UN1251	I	5, 7, 17, 19, 44, 72
Motor fuel antiknock mixture	6.1	UN1649	I	4, 17
Organochlorine pesticide, liquid, toxic	6.1	UN2996	I	3, 66
Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23°C (73°F)	6.1	UN2995	I	3, 66
Organochlorine pesticide, solid, toxic	6.1	UN2761	I	3, 66
Perchloromethyl mercaptan	6.1	UN1670	I	4, 17, 19, 44, 73
Phenylcarbylamine chloride	6.1	UN1672	I	4, 17, 19, 44, 73
Phenyl isocyanate	6.1	UN2487	I	4, 17, 19, 44, 73
Phenyl mercaptan	6.1	UN2337	I	4, 17, 19, 44, 73
Phosphorus trichloride	6.1	UN1809	I	4, 17, 19, 22, 44, 73
Potassium cyanide	6.1	UN1680	I	3, 42
n-Propyl chloroformate	6.1	UN2740	I	4, 17, 19, 44, 73
n-Propyl isocyanate	6.1	UN2482	I	5, 7, 17, 19, 44, 72
Sodium cyanide	6.1	UN1689	I	3, 42
Sulphuryl chloride	6.1	UN1834	I	5, 7, 14, 17, 19, 44, 72
Thiophosgene	6.1	UN2474	I	4, 17, 19, 44, 73
Titanium tetrachloride	8	UN1838	I	4, 15, 17, 19, 44, 73
Toxic liquid, flammable, organic, n.o.s.	6.1	UN2929	I	3, 66
Toxic, liquid, organic, n.o.s.	6.1	UN2810	I	3, 66
Toxic, solid, organic, n.o.s.	6.1	UN2811	I	3, 66
Toxic by inhalation, liquid, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50	6.1	UN3381	I	5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50	6.1	UN3382	I	4, 17, 19, 44, 73
Toxic by inhalation, liquid, flammable, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50	6.1	UN3383	I	5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, flammable, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50	6.1	UN3384	I	4, 17, 19, 44, 73
Toxic by inhalation, liquid, water reactive, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50	6.1	UN3385	I	5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, water reactive, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50	6.1	UN3386	I	4, 17, 19, 44, 73
Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50	6.1	UN3387	I	5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, oxidizing, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50	6.1	UN3388	I	4, 17, 19, 44, 73
Toxic by inhalation, liquid, corrosive, n.o.s., with an LC50 lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50	6.1	UN3389	I	5, 7, 17, 19, 44, 72
Toxic by inhalation, liquid, corrosive, n.o.s., with an LC50 lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50	6.1	UN3390	I	4, 17, 19, 44, 73
Trimethyl acetyl chloride	6.1	UN2438	I	4, 17, 19, 44, 73
Dangerous Goods of Class 6.1, Packing Group I, Liquids, not listed above	6.1	—	I	3
Dangerous Goods of Class 6.1, Packing Group I, Solids, not listed above	6.1	—	I	2

Class 6.1 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Allyl isothiocyanate, stabilized	6.1	UN1545	II	4, 17, 19
Benzyl chloride	6.1	UN1738	II	3, 43
Bromoacetone	6.1	UN1569	II	P
n-Butyl chloroformate	6.1	UN2743	II	4, 17, 19, 44, 73
Carbon tetrachloride	6.1	UN1846	II	3, 66
Chloroacetonitrile	6.1	UN2668	II	4, 17, 19, 44, 73
Chloroanilines, solid	6.1	UN2018	II	3, 66
Chlorocresols solution	6.1	UN 2669	II	3, 66
Chlorocresols, solid	6.1	UN3437	II	3, 66
Dibromochloropropanes	6.1	UN2872	II	3, 66
Dichloroisopropyl ether	6.1	UN2490	II	3, 66
Ethylene chlorohydrin	6.1	UN1135	II	4, 17, 19
Organochlorine pesticide, liquid, toxic	6.1	UN2996	II	3, 66
Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23°C (73°F)	6.1	UN2995	II	3, 66
Organochlorine pesticide, solid, toxic	6.1	UN2761	II	3, 66
Pentachloroethane	6.1	UN1669	II	3, 66
Phenol, molten	6.1	UN2312	II	3, 66
Toxic liquid, flammable, organic, n.o.s.	6.1	UN2929	II	3, 66
Toxic liquid, organic, n.o.s.	6.1	UN2810	II	3, 66
Toxic solid, organic, n.o.s.	6.1	UN2811	II	3, 66
Toluidines, liquid	6.1	UN1708	II	2
Dangerous Goods of Class 6.1, Packing Group II, Liquids, not listed above	6.1	—	II	3
Dangerous Goods of Class 6.1, Packing Group II, Solids, not listed above	6.1	—	II	2

Class 6.1 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Bromoform	6.1	UN2515	III	3, 66
Chlorocresols solution	6.1	UN 2669	III	3, 66
Chloroform	6.1	UN1888	III	3, 66
Chlorophenols, liquid	6.1	UN2021	III	3, 66
Dibromochloropropanes	6.1	UN2872	III	3, 66
Dibromomethane	6.1	UN2664	III	3, 66
o-Dichlorobenzene	6.1	UN1591	III	3, 66
Dichloromethane	6.1	UN1593	III	3, 66
Hexachlorobenzene	6.1	UN2729	III	3, 66
Hexachlorobutadiene	6.1	UN2279	III	3, 66
Hexachlorophene	6.1	UN2875	III	3, 66
Organochlorine pesticide, liquid, toxic	6.1	UN2996	III	3, 66
Organochlorine pesticide, liquid, toxic, flammable, flashpoint not less than 23°C (73°F)	6.1	UN2995	III	3, 66
Organochlorine pesticide, solid, toxic	6.1	UN2761	III	3, 66
Tetrachloroethylene	6.1	UN1897	III	3, 66
Toxic liquid, organic, n.o.s.	6.1	UN2810	III	3, 66
Toxic solid, organic, n.o.s.	6.1	UN2811	III	3, 66
1,1,1-Trichloroethane	6.1	UN2831	III	3, 66
Trichloroethylene	6.1	UN1710	III	3, 66
Dangerous Goods of Class 6.1, Packing Group III, Liquids, not listed above	6.1	—	III	2
Dangerous Goods of Class 6.1, Packing Group III, Solids, not listed above	6.1	—	III	1
Dangerous Goods of Class 6.1, Packing Group III, not listed above, with a subsidiary classification other than 9	6.1	—	III	3

Class 8 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Boron tribromide	8	UN2692	I	4, 17, 19, 44, 73
Bromine or Bromine solution	8	UN1744	I	10, 17, 72
Bromine solution	8	UN1744	I	10, 17, 73
Chlorosulphonic acid, with or without sulphur trioxide	8	UN1754	I	4, 17, 19, 44, 73
Chromosulphuric acid	8	UN2240	I	3, 14
Fluorosulphonic acid	8	UN1777	I	3, 14
Hydrazine, anhydrous	8	UN2029	I	3, 21, 32
Hydrazine, aqueous solution, with more than 37% hydrazine, by mass	8	UN2030	I	3, 21, 32
Hydrazine, aqueous solution, flammable with more than 37% hydrazine, by mass	8	UN2030	I	3, 21, 32
Hydrofluoric acid and sulphuric acid mixture	8	UN1786	I	3, 20, 23
Hydrofluoric acid solution, more than 60% hydrogen fluoride	8	UN1790	I	3, 20, 23
Hydrogen fluoride, anhydrous	8	UN1052	I	4, 15, 44, 74
Nitrating acid mixtures, more than 50% nitric acid	8	UN1796	I	3
Nitric acid, other than red fuming, with more than 70% nitric acid	8	UN2031	I	3, 32
Nitric acid, red, fuming	8	UN2032	I	4, 17, 44, 73
Sulphuric acid, fuming, greater than or equal to 30% free sulphur trioxide	8	UN1831	I	4, 17, 19, 44, 73
Sulphuric acid, fuming, less than 30% free sulphur trioxide	8	UN1831	I	3, 49
Sulphur trioxide, stabilized	8	UN1829	I	4, 17, 19, 31, 44, 73
Thionyl chloride	8	UN1836	I	3, 14
Dangerous Goods of Class 8, Packing Group I, not listed above	8	—	I	3

Class 8 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Allyltrichlorosilane, stabilized	8	UN1724	II	3, 14
Amyltrichlorosilane	8	UN1728	II	3, 14
Battery fluid, acid or Sulphuric acid, with not more than 51% acid	8	UN2796	II	3, 20
Boron trifluoride acetic acid complex	8	UN1742	II	3, 14
Butyltrichlorosilane	8	UN1747	II	3, 14
Chlorophenyltrichlorosilane	8	UN1753	II	3, 14
Dichloroacetyl chloride	8	UN1765	II	3, 14
Dichlorophenyltrichlorosilane	8	UN1766	II	3, 14
Diethyldichlorosilane	8	UN1767	II	3, 14
Diphenyldichlorosilane	8	UN1769	II	4, 8
Dodecyltrichlorosilane	8	UN1771	II	3, 14
Ethyl chlorothioformate	8	UN2826	II	4, 17, 19, 44, 73
Fluoroboric acid	8	UN1775	II	3, 20
Fluosilicic acid	8	UN1778	II	3, 20
Formic acid, with more than 85% acid by mass	8	UN1779	II	3, 27
Hexadecyltrichlorosilane	8	UN1781	II	3, 14
Hexyltrichlorosilane	8	UN1784	II	3, 14
Hydrazine, aqueous solution, with more than 37% hydrazine, by mass	8	UN2030	II	3, 21, 32
Hydrobromic acid	8	UN1788	II	3, 20
Hydrochloric acid	8	UN1789	II	3, 20
Hydrofluoric acid solution, not more than 60% hydrogen fluoride	8	UN1790	II	3, 20
Hypochlorite solution	8	UN1791	II	3, 20
Iodine monochloride	8	UN1792	II	3, 14
Nitrating acid mixtures, not more than 50% nitric acid	8	UN1796	II	3
Nitric acid, other than red fuming, with not more than 70% nitric acid	8	UN2031	II	3, 32
Nonyltrichlorosilane	8	UN1799	II	3, 14
Octadecyltrichlorosilane	8	UN1800	II	3, 14
Octyltrichlorosilane	8	UN1801	II	3, 14
Phenylphosphorus dichloride	8	UN2798	II	3, 20
Phenylphosphorus thiodichloride	8	UN2799	II	3, 20
Phenyltrichlorosilane	8	UN1804	II	3, 14
Phosphorus oxybromide	8	UN1939	II	1, 16
Phosphorus oxybromide, molten	8	UN2576	II	3, 16
Phosphorus oxychloride	8	UN1810	II	4, 17, 19, 44, 73
Phosphorus tribromide	8	UN1808	II	3, 24
Propyltrichlorosilane	8	UN1816	II	3, 14
Silicon tetrachloride	8	UN1818	II	3, 14
Sulphuric acid, spent	8	UN1832	II	3, 49, 50
Sulphuric acid, with more than 51% acid	8	UN1830	II	3, 49, 50
Thiophosphoryl chloride	8	UN1837	II	3, 16, 24
Trichloroacetyl chloride	8	UN2442	II	4, 17, 19, 44, 73
Vanadium oxytrichloride	8	UN2443	II	3, 21
Dangerous Goods of Class 8, Packing Group II, Liquids, not listed above	8	—	II	3
Dangerous Goods of Class 8, Packing Group II, Solids, not listed above	8	—	II	1

Class 8 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Ferric chloride solution	8	UN2582	III	2, 20
Hydrazine, aqueous solution, with more than 37% hydrazine, by mass	8	UN2030	III	3, 21, 32
Hydrobromic acid	8	UN1788	III	3, 20
Hydrochloric acid	8	UN1789	III	3, 20
Dangerous Goods of Class 8, Packing Group III, Liquids, not listed above	8	—	III	2
Dangerous Goods of Class 8, Packing Group III, Solids, not listed above	8	—	III	1

Class 9 Packing Group I Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Dangerous Goods of Class 9, Packing Group I, Liquids	9	—	I	2
Dangerous Goods of Class 9, Packing Group I, Solids	9	—	I	1

Class 9 Packing Group II Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Blue asbestos (crocidolite) or Brown asbestos (amosite, mysorite)	9	UN2212	II	1, 71
Polychlorinated biphenyls, Liquids	9	UN2315	II	3, 66
Dangerous Goods of Class 9, Packing Group II, Liquids, not listed above	9	—	II	2
Dangerous Goods of Class 9, Packing Group II, Solids, not listed above	9	—	II	1

Class 9 Packing Group III Dangerous Goods

Column 1 Shipping Name and Description	Column 2 Primary Class	Column 3 UN Number	Column 4 Packing Group	Column 5 Special Provision
Elevated temperature liquid, n.o.s., at or above 100°C (212°F) and below its flashpoint including molten metals, molten salts, etc.	9	UN3257	III	67
Elevated temperature solid, n.o.s., at or above 240°C (464°F)	9	UN3258	III	68
Environmentally hazardous substance, solid, n.o.s.	9	UN3077	III	1, 33
White asbestos (chrysotile, actinolite, anthophyllite, tremolite)	9	UN2590	III	1, 71
Dangerous Goods of Class 9, Packing Group III, Liquids, not listed above	9	—	III	2
Dangerous Goods of Class 9, Packing Group III, Solids, not listed above	9	—	III	1